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Reaction of methoxyphenylcarbenepentacarbonyltungsten with tetrachloromethane and the catalytic activity of the system formed relative to the polymerization of cycloolefins with ring opening

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The catalytic system formed in the reaction of the methoxyphenylcarbene complex of pentacarbonyltungsten with tetrachloromethane is active for the polymerization of 1,5-cyclooctadiene with ring opening.

  2. 2.

    A study of the products of the reaction of this complex with tetrachloromethane indicated that the catalytically active species in such reactions are intermediate chlorocarbene complexes.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. P. Kolesnikov, T. L. Mitenina, S. A. Radzinskii, A. P. Sheinker, A. D. Abkin & O. M. Nefedov

  2. L. Ya. Karpov Institute of Physical Chemistry, Moscow

    S. P. Kolesnikov, T. L. Mitenina, S. A. Radzinskii, A. P. Sheinker, A. D. Abkin & O. M. Nefedov

Authors
  1. S. P. Kolesnikov
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  2. T. L. Mitenina
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  3. S. A. Radzinskii
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  4. A. P. Sheinker
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  5. A. D. Abkin
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  6. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2303–2307, October, 1981.

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Kolesnikov, S.P., Mitenina, T.L., Radzinskii, S.A. et al. Reaction of methoxyphenylcarbenepentacarbonyltungsten with tetrachloromethane and the catalytic activity of the system formed relative to the polymerization of cycloolefins with ring opening. Russ Chem Bull 30, 1892–1895 (1981). https://doi.org/10.1007/BF00963417

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  • DOI: https://doi.org/10.1007/BF00963417

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