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Polymerization of 1,2-dimethylenecyclobutane

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    From their1H and13C NMR spectra, polymers of 1,2-dimethylenecyclobutane obtained by radical polymerization contain 85–90% of units containing the cyclobutene and 10–15% of units with the methylenecyclobutane structure.

  2. 2.

    The presence in the polymer of 1,2-dimethylenecyclobutane of cyclobutene units capable of isomerizing on heating to 150°C to give exodiene structures enables it to undergo thermal cross-linking and addition of maleic anhydride.

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Literature cited

  1. A. T. Blomquist and J. A. Verdol, J. Am. Chem. Soc.,77, 1806 (1955).

    Google Scholar 

  2. A. P. Khitrov, Thesis, All-Union Scientific-Research Institute for Petroleum Chemistry, Leningrad (1963).

    Google Scholar 

  3. Ngo Zui Kyong, Yu. V. Korshak, G. N. Bondarenko, M. P. Teterina, and B. A. Dolgoplosk, Vysokomol. Soedin.,B15, 375 (1973).

    Google Scholar 

  4. V. T. Aleksanyan and O. G. Garkusha, Izv. Akad. Nauk SSSR, Ser. Khim., 2227 (1976).

  5. L. Bellamy, New Data on the Infra-Red Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971), p. 36.

    Google Scholar 

  6. C. C. Wu and R. W. Lenz, J. Polym. Sci., Polym. Chem. Ed.,10, 3555 (1972).

    Google Scholar 

  7. H. M. Frey, D. C. Montague, and I. D. R. Stevens, Trans. Faraday Soc.,63, 372 (1967).

    Google Scholar 

  8. Ya. M. Slobodin, and A. P. Khitrov, Zh. Obshch. Khim.,33, 2822 (1963).

    Google Scholar 

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Authors and Affiliations

  1. A. V. Topchiev Institute for Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    T. G. Golenko, G. N. Bondarenko, K. L. Makovetskii, V. A. Dolgoplosk, A. V. Yurkovetskii, A. M. Taber & I. V. Kalechits

Authors
  1. T. G. Golenko
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  2. G. N. Bondarenko
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  3. K. L. Makovetskii
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  4. V. A. Dolgoplosk
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  5. A. V. Yurkovetskii
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  6. A. M. Taber
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  7. I. V. Kalechits
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2296–2299, October, 1981.

The authors express their great indebtedness to A. S. Khachaturov and A. Yu. Koshevnik for the recording and interpretation of the NMR spectra.

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Golenko, T.G., Bondarenko, G.N., Makovetskii, K.L. et al. Polymerization of 1,2-dimethylenecyclobutane. Russ Chem Bull 30, 1886–1889 (1981). https://doi.org/10.1007/BF00963415

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  • DOI: https://doi.org/10.1007/BF00963415

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