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Carbonylation of branched olefins in the presence of BF3·H2O and ethyl formate at atmospheric pressure

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The carbonylation of branched olefins using ethyl formate occurs in one stage at atmospheric pressure in the presence of BF3·H2O as catalyst with the production of the ethyl esters ofα, α-branched carboxylic acids in yields up to 50–70%.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. D. Pirozhkov, A. S. Stepanyan, M. B. Ordyan & A. L. Lapidus

  2. Yerevan Medical Institute, USSR

    S. D. Pirozhkov, A. S. Stepanyan, M. B. Ordyan & A. L. Lapidus

Authors
  1. S. D. Pirozhkov
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  2. A. S. Stepanyan
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  3. M. B. Ordyan
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  4. A. L. Lapidus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2292–2295, October, 1981.

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Pirozhkov, S.D., Stepanyan, A.S., Ordyan, M.B. et al. Carbonylation of branched olefins in the presence of BF3·H2O and ethyl formate at atmospheric pressure. Russ Chem Bull 30, 1883–1886 (1981). https://doi.org/10.1007/BF00963414

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  • DOI: https://doi.org/10.1007/BF00963414

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