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Comparison of the retention indices and differential molar free energies of solution for thiolic and carboxylic esters on gas-chromatographic columns with various polarities

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    There is no full analogy between the gas-chromatographic behavior of thiolic and carboxylic esters.

  2. 2.

    The retention indices of 24 thiolic esters were determined on columns of Apiezon M, silicone OV-17, Triton X-305, and polyethylene glycol 1000 at 130°C.

  3. 3.

    Equations are proposed for the dependence of the retention indices on the number of carbon atoms in the n-alkyl chain on four stationary phases for the homologous series of n-alkyl thioacetates. The equations can be used for the identification of n-alkyl thioacetates in mixtures of sulfur-containing compounds.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. V. Golovnya, V. G. Garbuzov & A. F. Aérov

Authors
  1. R. V. Golovnya
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  2. V. G. Garbuzov
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  3. A. F. Aérov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2284–2288, October, 1981.

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Golovnya, R.V., Garbuzov, V.G. & Aérov, A.F. Comparison of the retention indices and differential molar free energies of solution for thiolic and carboxylic esters on gas-chromatographic columns with various polarities. Russ Chem Bull 30, 1877–1880 (1981). https://doi.org/10.1007/BF00963412

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  • DOI: https://doi.org/10.1007/BF00963412

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