Conclusions
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1.
The direction of the molecular moment of N,N-dimethylbenzamide constitutes an angle of 53° with the N-C bond.
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2.
The carbon-halogen bonds in N-(halomethyl)benzamides are turned by 90 ± 8° with respect to the plane of the amide group.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2264–2266, October, 1981.
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Nasyrov, D.M., Vereshchagin, A.N. Conformations of N-(halomethyl) benzamides. Russ Chem Bull 30, 1859–1861 (1981). https://doi.org/10.1007/BF00963408
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DOI: https://doi.org/10.1007/BF00963408