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Preparation of complexes of π-allylpalladium chloride with ferrocenylphosphine ligands and investigation of retarded rotation around Pd-P bond

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Complexes of π-allylpalladium chloride with ferrocenylphosphin.es have been synthesized.

  2. 2.

    By means of PMR spectroscopy, an assignment has been made for the α and β protons of the substituted ring in the coordinated triferrocenylphosphine.

  3. 3.

    By means of dynamic NMR, rotation around the Pd-P bond in π-C3H5PdClP(Fc)3 has been studied in various solvents, and the activation characteristics of the process have been determined.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. S. Tolkunova, A. Z. Rubezhov, V. I. Bakhmutov & V. D. Vil'chevskaya

Authors
  1. V. S. Tolkunova
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  2. A. Z. Rubezhov
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  3. V. I. Bakhmutov
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  4. V. D. Vil'chevskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2228–2231, October, 1981.

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Tolkunova, V.S., Rubezhov, A.Z., Bakhmutov, V.I. et al. Preparation of complexes of π-allylpalladium chloride with ferrocenylphosphine ligands and investigation of retarded rotation around Pd-P bond. Russ Chem Bull 30, 1826–1830 (1981). https://doi.org/10.1007/BF00963401

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  • DOI: https://doi.org/10.1007/BF00963401

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