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Decay kinetics of branched fluorine-containing radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The mechanism and rate of decay of fluorine-containing cumyl radicals depends on the type of substituent in the para position.

  2. 2.

    The dimerization rate of perfluoro-tert-butyl radicals is limited by diffusion and depends on the concentration of pyridine which forms a weak complex with the radical.

  3. 3.

    Perfluorocumyl radicals do not dimerize.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    B. L. Tumanskii, N. N. Bubnov, V. R. Polishchuk & S. P. Solodovnikov

Authors
  1. B. L. Tumanskii
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  2. N. N. Bubnov
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  3. V. R. Polishchuk
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  4. S. P. Solodovnikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2222–2227, October, 1981.

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Tumanskii, B.L., Bubnov, N.N., Polishchuk, V.R. et al. Decay kinetics of branched fluorine-containing radicals. Russ Chem Bull 30, 1821–1826 (1981). https://doi.org/10.1007/BF00963400

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  • DOI: https://doi.org/10.1007/BF00963400

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