Skip to main content
Log in

Preparation of alkali-metal aluminohydrides and gallohydrides

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Pure aluminohydrides and gallohydrides of potassium, rubidium, and cesium can be obtained with high yields by means of the reactions of NaEH4 (E=Al, Ga) with the appropriate alkalimetal chloride in THF.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. H. Clasen, Angew. Chem.,73, 322 (1961).

    Google Scholar 

  2. T. N. Dymova, M. S. Selivokhina, N. G. Eliseeva, and N. T. Osipenko, Inventor s Certificate No. 259,060 (1963); Byull. Izobr., No. 3, 208 (1974).

  3. V. V. Gavrilenko, Yu. N. Karaksin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1838 (1971).

  4. T. N. Dymova and Yu. M. Dergachev, Inventor's Certificate No. 364,562 (1971); Byull. Izobr., No. 5, 66 (1973).

  5. L. I. Zakharkin and V. V. Gavrilenko, Dokl. Akad. Nauk SSSR,145, 793 (1962).

    Google Scholar 

  6. S. I. Bakum, U. Mirsaidov, S. F. Ereshko, and T. N. Dymova, Inventor's Certificate No. 521,221 (1973); Byull. Izobr. No. 26, 68 (1976).

  7. L. I. Zakharkin, V. V. Gavrilenko, and Yu. N. Karaksin, Inorg. Metal.-Org. Chem., 1 (1), 37 (1971).

    Google Scholar 

  8. L. I. Zakharkin and V. V. Gavrilenko, Zh. Neorg. Khim.,11, 977 (1966).

    Google Scholar 

  9. L. I. Zakharkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1146 (1962).

  10. L. I. Zakharkin, V. V. Gavrilenko, and Yu. N. Karaksin, Zh. Obshch. Khim.,41, 2689 (1971).

    Google Scholar 

  11. S. I. Bakum and S. F. Ereshko, Zh. Neorg. Khim.,22, 655 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2183–2185, October, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bakum, S.I., Ereshko, S.F. Preparation of alkali-metal aluminohydrides and gallohydrides. Russ Chem Bull 30, 1787–1788 (1981). https://doi.org/10.1007/BF00963391

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00963391

Keywords

Navigation