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Synthesis of 6-formyl-2,3-di-o-phenylcarbamoylcellulose and its conversion into a 6-amino-6-desoxypolysaccharide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The compound 6-formyl-2,3-di-O-phenylcarbamoylcellulose has been prepared with degree of oxidation 0.7–0.8 during the oxidation of 2,3-di-O-phenylcarbamoylcellulose by the mixtures DMSO-DCHC-PSFA and DMSO-P2O5 (DCHC is dicyclohexylcarbodiimide, and PSFA is the pyridine salt of trifluoroacetic acid).

  2. 2.

    Upon the reduction of 6-aldoxime-2,3-di-O-phenylcarbamoylcellulose by LiAlH4, a 6-amino-6-desoxysaccharide is obtained with degree of substitution of 0.45.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Z. I. Kuznetsova

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  1. Z. I. Kuznetsova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1101–1103, May, 1979.

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Kuznetsova, Z.I. Synthesis of 6-formyl-2,3-di-o-phenylcarbamoylcellulose and its conversion into a 6-amino-6-desoxypolysaccharide. Russ Chem Bull 28, 1029–1031 (1979). https://doi.org/10.1007/BF00963323

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  • DOI: https://doi.org/10.1007/BF00963323

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