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Determination of volume effects in initiation activation in the decomposition of azoisobutyric acid dinitrile in styrene and methylmethacrylate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2,2,6,6-Tetramethylpiperidin-1-oxyl can be used for quantitative determination of the volume change accompanying initiation activation (ΔVi ≠).

  2. 2.

    The value of (ΔVi ≠) for the decomposition of azoisobutyric acid dinitrile is essentially the same in styrene and in methyl methacrylate.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. M. Zhulin, G. A. Stashina & É. G. Rozantsev

  2. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. M. Zhulin, G. A. Stashina & É. G. Rozantsev

Authors
  1. V. M. Zhulin
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  2. G. A. Stashina
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  3. É. G. Rozantsev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 977–982, May, 1979.

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Zhulin, V.M., Stashina, G.A. & Rozantsev, É.G. Determination of volume effects in initiation activation in the decomposition of azoisobutyric acid dinitrile in styrene and methylmethacrylate. Russ Chem Bull 28, 914–919 (1979). https://doi.org/10.1007/BF00963296

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  • DOI: https://doi.org/10.1007/BF00963296

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