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Diels-Alder reaction of 16-dehydropregnenolone acetate with 1,2-dimethylenecyclobutane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

16-Dehydropregnenolone acetate undergoes condensation with 1,2-dimethylenecyclobutane in the presence of a Lewis acid to form a 16α,17α-monoadduct, namely, 3′,4′-ethano-16α,17α-cyclohex-3′-enopregn-5-en-3β-ol-20-one acetate.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, V. N. Ignatov, I. S. Levina, V. S. Bogdanov & E. G. Cherepanov

Authors
  1. A. V. Kamernitskii
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  2. V. N. Ignatov
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  3. I. S. Levina
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  4. V. S. Bogdanov
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  5. E. G. Cherepanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2397–2399, October, 1985.

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Kamernitskii, A.V., Ignatov, V.N., Levina, I.S. et al. Diels-Alder reaction of 16-dehydropregnenolone acetate with 1,2-dimethylenecyclobutane. Russ Chem Bull 34, 2221–2222 (1985). https://doi.org/10.1007/BF00963268

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  • DOI: https://doi.org/10.1007/BF00963268

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