Conclusions
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1.
Aliphatic N-nitramines in methane plasma form stable protonated molecular ions which often form the most intense peaks in the chemical ionization mass spectra.
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2.
The fragmentation of the protonated molecular ions of aliphatic N-nitramines proceeds largely with the breakage of a C-N bond and the formation of a hydrocarbon radical-ion.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khlmicheskaya, No. 10, pp. 2394–2397, October, 1985.
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Chizhov, O.S., Kadentsev, V.I., Shevelev, S.A. et al. Chemical ionization mass spectrometric study of aliphatic nitramines. Russ Chem Bull 34, 2217–2220 (1985). https://doi.org/10.1007/BF00963267
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DOI: https://doi.org/10.1007/BF00963267