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Formation of palladium hydride complexes upon the reduction of Pd(II) by hydrogen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reduction of palladium(II) acetate by hydrogen in the presence of 1,10-phenanthroline or 2,2′-dipyridyl gives palladium hydride clusters containing a massive metal-like nucleus with interstitial hydrogen atoms. The ligands are found to be peripheral palladium atoms, while the acetate groups are found in the external sphere.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, D. I. Kochubei, V. M. Nekipelov, V. M. Mastikhin, V. D. Chinakov, K. I. Zamaraev & I. I. Moiseev

  2. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, D. I. Kochubei, V. M. Nekipelov, V. M. Mastikhin, V. D. Chinakov, K. I. Zamaraev & I. I. Moiseev

Authors
  1. M. N. Vargaftik
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  2. V. P. Zagorodnikov
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  3. I. P. Stolyarov
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  4. D. I. Kochubei
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  5. V. M. Nekipelov
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  6. V. M. Mastikhin
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  7. V. D. Chinakov
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  8. K. I. Zamaraev
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  9. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2381–2384, October, 1985.

The authors express their gratitude to S. G. Ellert for measuring the magnetic susceptibility and to A. L. Chuvilin for the electron microscopic data.

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Vargaftik, M.N., Zagorodnikov, V.P., Stolyarov, I.P. et al. Formation of palladium hydride complexes upon the reduction of Pd(II) by hydrogen. Russ Chem Bull 34, 2206–2209 (1985). https://doi.org/10.1007/BF00963263

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  • DOI: https://doi.org/10.1007/BF00963263

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