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Replacement of the stannyl group in X3SnRe(co)5 complexes by the action of amino acids and their derivatives

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of stannyl derivatives of rhenium carbonyl of the type X3SnRe(CO)5 (X=Ph or Hal) with amino acids and their derivatives (esters, salts) proceed with fission of the metal-metal bond and with the formation of amino acid derivatives of rhenium carbonyl with a facial disposition of CO groups in the Re(CO)3 fragment.

  2. 2.

    An organometallic complex with a Sn-Re bond was obtained by an insertion reaction of SnCl2 at the Cl-Re bond in the methyl L-leucinate derivative of rhenium carbonyl chloride. The complex contained coordinated amino groups of the leucine ester molecule as ligands.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Academy of Sciences of the USSR, Krasnoyarsk

    Yu. G. Kovalev & A. A. Johansson

Authors
  1. Yu. G. Kovalev
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  2. A. A. Johansson
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2372–2376, October, 1985.

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Kovalev, Y.G., Johansson, A.A. Replacement of the stannyl group in X3SnRe(co)5 complexes by the action of amino acids and their derivatives. Russ Chem Bull 34, 2197–2200 (1985). https://doi.org/10.1007/BF00963261

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  • DOI: https://doi.org/10.1007/BF00963261

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