Conclusions
Addition of ethylmercaptan to fluorinatedβ-diketones proceeds through the enol form at the carbon atom bound to the fluoroalkyl substituent; with fluorinatedβ-ketoesters it is also the enol form which reacts with the mercaptan.
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Literature cited
Beilstein's Handbuch der Organische Chemie, Vol. 1, Berlin (1918), p. 777.
R. Escales and E. Baumann, Chem. Ber.,19, 1787 (1886).
F. Bossert, Ann. Chem.,680, 40 (1964).
K. I. Pashkevich, A. N. Fomin, V. I. Saloutin, D. V. Bazhenov, and Yu. K. Grishin, Izv. Akad. Nauk SSR, Ser. Khim., 1359 (1982).
A. N. Fomin, V. I. Saloutin, K. I. Pashkevich, D. V. Bazhenov, Yu. K. Grishin, and Y. A. Ustynyuk, Izv. Akad. Nauk SSR, Ser. Khim., 2626 (1983).
F. Camps, J. Coll, A. Messequer, and A. Roca, Tetrahedron,33, 1637 (1977).
K. I. Pashkevich, V. I. Saloutin, and I. Y. Postovskii, Zh. Org. Khim.,13, 49 (1977).
A. L. Henne, M. S. Newman, L. L. Quill, and R. N. Staniforth, J. Am. Chem. Soc.,69, 1819 (1947).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2293–2298, October, 1985.
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Pashkevich, K.I., Fomin, A.N., Saloutin, V.I. et al. Reaction of fluorinated β-dicarbonyl compounds with ethylmercaptan. Russ Chem Bull 34, 2123–2127 (1985). https://doi.org/10.1007/BF00963247
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DOI: https://doi.org/10.1007/BF00963247