Conclusions
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1.
By using a catalyst containing palladium bis(acetylacetonate) and triphenylphosphine linear unsaturated C9 acids and 3-ethylidene-5-propenylbutyrolactone can be obtained in a high yield from CO2 and butadiene in dimethylformamide.
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2.
Under the reaction conditions, low-valence phosphonic complexes of palladium catalyze the oxidation of triphenylphosphine to triphenylphosphine oxide and the reduction of CO2 to CO.
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Literature cited
M. E. Vol'pin, Pure Appl. Chem.,30, 607 (1972).
M. E. Vol'pin, I. S. Kolomnikov, and T. S. Loboeva, Izv. Akad. Nauk SSSR, Ser. Khim., 2084 (1969).
I. S. Kolomnikov, T. S. Loveeva, and M. E. Vol'pin, Izv. Akad. Nauk SSSR, Ser. Khim., 2650 (1970).
M. E. Vol'pin and I. S. Kolomnikov, Organomet. React.,5, 313 (1975).
M. E. Vol'pin, Z. Chem.,12, 361 (1972).
Y. Inoue, T. Hibi, M. Satake, and H. Hashimoto, J. Chem. Soc. Chem. Commun., 982 (1978).
A. Lapidus, S. D. Pirozhkov, and A. A. Koryakin, Izv. Akad. Nauk SSSR, Ser. Khim., 2814 (1978).
Y. Inoue, Y. Iton, and H. Hashimoto, Chem. Lett., 633 (1978).
Y. Inoue, Y. Iton, H. Kazama, and H. Hashimoto, Bull. Chem. Soc. Jpn.,53, 3329 (1980).
A. Döring and P. W. Jolly, Tetrahedron Lett.,21, 3021 (1980).
Y. Sasaki, Y. Inoue, and H. Hashimoto, J. Chem. Soc. Chem. Commun., 605 (1976).
Y. Inoue, Y. Sasaki, and H. Hashimoto, Bull. Chem. Soc. Jpn.,51, 2375 (1978).
A. Musco, C. Perego, and V. Tartiary, Inorg. Chim. Acta,28, 147 (1978).
A. Musco, J. Chem. Soc., Perkin Trans. 1, 693 (1980).
I. A. Daniels, Eur. Pat. Appl. EP 50445 (1982).
A. Behr, K.-D. Juszak, and W. Keim, Synthesis7, 574 (1983).
A. Behr and K.-D. Juszak, J. Organomet. Chem.,255, 263 (1983).
Y. Onoue, S. Sekiya, Y. Sasaki, and H. Hashimoto, J. Synth. Org. Chem. Jpn.,36, 328 (1978); Chem. Abstr.,89, 42280 (1978).
Y. M. Dzhemilev, V. V. Sidorova, and R. V. Kunakova, Izv. Akad. Nauk SSSR, Ser. Khim., 584 (1983).
K. M. Nickolas, J. Organomet. Chem.,188 C10 (1980).
U. M. Dzhemilev, L. G. Kunakova, Yu. T. Struchkov, G. A. Tolstikov, F. V. Sharipova, L. G. Kuz'mina, and S. R. Rafikov, Dokl. Akad. Nauk SSSR,250, 105 (1980).
F. M. Rapoport and A. A. Il'inskaya, Laboratory Methods for Preparation of Pure Gases [in Russian], Goskhimizdat, Moscow (1963).
Yu. M. Kargin, V. Z. Kondranina, and G. M. Semakhina, Izv. Akad. Nauk SSSR, Ser. Khim., 278 (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2273–2276, October, 1985.
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Dzhemilev, U.M., Kunakova, R.V. & Sidorova, V.V. Activation of CO2 in reaction with butadiene catalyzed by palladium complexes. Russ Chem Bull 34, 2102–2106 (1985). https://doi.org/10.1007/BF00963243
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DOI: https://doi.org/10.1007/BF00963243