Conclusions
The selective catalytic epoxidation of 1-alkenes by molecular oxygen was accomplished in the presence of C2-C5 alipahtic aldehydes and catalysts, viz., the salts of Cu(II), Ni(II), Fe(III), or Zr(IV).
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
P. I. Valov, É. A. Blyumberg, and N. M. Émanuél', Izv. Akad. Nauk SSSR, Ser. Khim., 583 (1966).
P. I. Valov, É. A. Blyumberg, and N. M. Émanuél', Izv. Akad. Nauk SSSR, Ser. Khim., 791 (1969).
Pat. No. 2752920 (FRG); Chem. Abs.,91, 107880 (1979).
Pat. No. 3379737 (USA).
Pat. No. 3699133 (USA).
M. G. Vinogradov, I. P. Kovalev, and G. I. Nikishin, Inventor's Certificate No. 1051086 (USSR); Byull. Izobret., No. 40, 94 (1983).
S. A. Maslov, S. A. Vasil'chenko, É. A. Blyumberg, and V. G. Dryuk, Izv. Akad. Nauk SSSR, Ser. Khim., 2467 (1972).
M. G. Vinogradov, I. P. Kovalev, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 1569 (1981).
M. G. Vinogradov, R. V. Kereselidze, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 1195 (1971).
G. Ferrandi, Inorg. Chem.,17, 2506 (1978).
M. Freiberg and D. Meyerstein, Chem. Comm., 127 (1977).
B. A. Dolgopolosk and E. I. Tinyakova, Redox Systems as Sources of Free Radicals [in Russian], Nauka, Moscow (1972), Chap. 3.
N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Chain Reactions of the Oxidation of Hydrocarbons in the Liquid Phase [in Russian], Nauka, Moscow (1965), p. 218.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2269–2272, October, 1985.
Rights and permissions
About this article
Cite this article
Vinogradov, M.G., Kovalev, I.P. & Nikishin, G.I. Synthesis of higher epoxides by the joint catalytic oxidation of aldehydes and olefins. Russ Chem Bull 34, 2098–2102 (1985). https://doi.org/10.1007/BF00963242
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00963242