Conclusions
In a series of compounds with fragments OCsp3-Cl or OCsp2-Cl, O=CCl, the relationships observed in the changes in35Cl NQR frequencies are explained by geometric and energy characteristics of the orbitals n(0) andσ*(CCl).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2204–2207, October, 1985.
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Bredikhin, A.A., Andreeva, A.I., Safin, I.A. et al. 35Cl NQR of cyclic α-chlorovinyl ethers and orbital interactions in O-C-Cl triad. Russ Chem Bull 34, 2037–2040 (1985). https://doi.org/10.1007/BF00963228
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DOI: https://doi.org/10.1007/BF00963228