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Kinetics and intermediate products in the interaction of straight-chain and cyclic hydrocarbon radicals with 9,10-anthraquinone

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of cyclododecyl and n-dodecyl radicals with 9,10-anthraquinone in the corresponding liquid hydrocarbons, which has been investigated by means of pulse radiolysis, goes forward with rate constants from 109 to 1010 liters/mole·sec and is accompanied by the formation of adducts — apparently, charge transfer complexes.

  2. 2.

    In the presence of oxygen, hydrocarbon radicals with the quinone form oxygen-containing species that are capable of propagating the oxidation chain and regenerating the original quinone.

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Authors and Affiliations

  1. State Scientific-Research and Design Institute of the Nitrogen Industry and Products of Organic Synthesis, Moscow

    B. Ya. Ladygin & A. A. Revina

  2. A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    B. Ya. Ladygin & A. A. Revina

Authors
  1. B. Ya. Ladygin
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  2. A. A. Revina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2180–2186, October, 1985.

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Ladygin, B.Y., Revina, A.A. Kinetics and intermediate products in the interaction of straight-chain and cyclic hydrocarbon radicals with 9,10-anthraquinone. Russ Chem Bull 34, 2013–2019 (1985). https://doi.org/10.1007/BF00963224

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  • DOI: https://doi.org/10.1007/BF00963224

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