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Polymer Bulletin

, Volume 35, Issue 3, pp 271–277 | Cite as

Copolymerization without initiator ofN-(2-hydroxyethyl)ethyleneimine with succinic anhydride

  • S. A. Pooley
  • G. S. Canessa
  • B. L. Rivas
  • E. Espejo
Article

Summary

Copolymers of N-(2-hydroxyethyl)ethyleneimine and succinic anhydride without initiator were prepared under different experimental conditions. The composition of the copolymers was determined by elemental analyses and1H-NMR spectroscopy. From the results of FT-IR and1H-NMR spectroscopy a scheme of copolymerization via zwitterion is presented which includes an esterification reaction of the pendant hydroxylic groups.

Keywords

Polymer Spectroscopy Anhydride Copolymerization Esterification Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    T. Saegusa,CHEMTECH,5, 295 (1975).Google Scholar
  2. 2.
    T. Saegusa, S. Kobayashi and Y. Kimura.Pure Appl. Chem.,48, 307 (1976).Google Scholar
  3. 3.
    G. Odian and P.A. Gunatillake.Macromolecules,18, 605 (1985).Google Scholar
  4. 4.
    B.L. Rivas, G.S. Canessa and S.A. Pooley.Polym. Bull. (Berlin),13, 65 (1985).Google Scholar
  5. 5.
    B.L. Rivas, G.S. Canessa, S.A. Pooley.Makromolek. Chem. Rapid Commun.,8, 365 (1987).Google Scholar
  6. 6.
    B.L. Rivas, G.S. Canessa, S.A. Pooley.Makromolek. Chem.,190, 2665 (1989).Google Scholar
  7. 7.
    B.L. Rivas, G.S. Canessa, S.A. Pooley.Eur. Polym. J.,25, 225 (1989).Google Scholar
  8. 8.
    B.L. Rivas, G.S. Canessa, S.A. Pooley.Bol. Soc. Chil. Quím.,36, 23 (1991).Google Scholar
  9. 9.
    B.L. Rivas, G.S. Canessa, S.A. Pooley.Eur. Polym. J.,28, 43 (1992).Google Scholar
  10. 10.
    S.A. Pooley, G.S. Canessa, B.L. Rivas.Eur. Polym. J.,29, 1239 (1993).Google Scholar
  11. 11.
    S.A. Pooley, G.S. Canessa, B.L. Rivas, E. Espejo.Bol. Soc. Chil. Quím.,39, 305 (1994).Google Scholar
  12. 12.
    Organikum”, VEB Deutscher Verlag der Wissenschaften, Berlin, 1972.Google Scholar
  13. 13.
    B.L. Rivas, K.E. Geckeler, E. Bayer.Eur. Polym. J.,27, 1165 (1991).Google Scholar
  14. 14.
    E. Presch, T. Clerc, J. Seibl and W. Simon.Table of Spectral Data for Structure Determination of Organic Compounds. Springer Verlag, Berlin (1983).Google Scholar

Copyright information

© Springer-Verlag 1995

Authors and Affiliations

  • S. A. Pooley
    • 1
  • G. S. Canessa
    • 1
  • B. L. Rivas
    • 1
  • E. Espejo
    • 1
  1. 1.Departmento de Polimeros, Facultad de Ciencias QuímicasUniversidad de ConcepciónConcepciónChile

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