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Ruthenium catalyzed regioselective step-growth copolymerization of 4′-methoxyacetophenone, or 4′-phenoxyacetophenone and α, ω-dienes

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Summary

Ruthenium catalyzed step growth copolymerization of 4′-methoxyacetophenone or 4′-phenoxyacetophenone and α,ω-dienes such as 1,3-divinyltetramethyldisiloxane or 3,3,6,6-tetramethyl-3,6-disila-1,7-octadiene give copolymers which have respectable molecular weights. The synthesis and characterization of these copolymers is reported. Higher molecular weight copolymers are quite thermally stable.

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Authors and Affiliations

  1. D. P. and K. B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA

    Hongjie Guo & William P. Weber

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  1. Hongjie Guo
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  2. William P. Weber
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Guo, H., Weber, W.P. Ruthenium catalyzed regioselective step-growth copolymerization of 4′-methoxyacetophenone, or 4′-phenoxyacetophenone and α, ω-dienes. Polymer Bulletin 35, 259–264 (1995). https://doi.org/10.1007/BF00963121

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  • DOI: https://doi.org/10.1007/BF00963121

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