Skip to main content
Log in

Electrode transformations of carbanions and heteroanions

1. Electrolytic synthesis of 1-phenyl-3-nitro-1,2,4-triazole and its1H,13C, and15N NMR spectra

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The electrolytic oxidation of the 3-nitro-1,2,4-triazole anion is realized through an intermediate radical, which splits out an H atom on reaction with the medium and reacts with benzene to give N-substituted phenyl-3-nitro-1,2,4-triazoles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. V. A. Petrosyan and M. E. Niyazymbetov, Izv. Akad. Nauk SSSR, Ser. Khim., 368 (1988).

  2. V. A. Petrosyan and M. E. Niyazymbetov, Izv. Akad. Nauk SSSR, Ser. Khim., 603 (1987).

  3. J. Elguero, C. Marzin, and J. Roberts, J. Org. Chem.,39, 357 (1974).

    Google Scholar 

  4. P. Dvortsak, J. Reiter, T. Somorai, and P. Sohar, Magn. Reson. Chem.,23, 194 (1985).

    Google Scholar 

  5. D. Wofford, D. Forkey, and J. Russel, J. Org. Chem.,47, 5132 (1982).

    Google Scholar 

  6. G. Hawkes, E. Randall, J. Elguero, and C. Marzin, J. Chem. Soc., Perkin Trans.2, 1024 (1977).

    Google Scholar 

  7. A. Fruchier, V. Pelegrin, R. Schimpt, and J. Elguero, Org. Magn. Reson.,48, 10 (1982).

    Google Scholar 

  8. T. Shono, S. Kashimura, and H. Nogusa, Chem. Lett., 425 (1986).

  9. L. I. Bagal, M. S. Pevzner, A. N. Frolova, and N. I. Sheludyakova, Khim. Geterotsikl. Soedin., 259 (1970).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1643–1646, July, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrosyan, V.A., Niyazymbetov, M.E., Pevzner, M.S. et al. Electrode transformations of carbanions and heteroanions. Russ Chem Bull 37, 1458–1461 (1988). https://doi.org/10.1007/BF00962762

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962762

Keywords

Navigation