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Synthesis and crystal structure of cyclotris(m-phenylenesulfide)

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Using a fractional extraction method, a macrocyclic trimer, cyclotris(m-phenylenesulfide), has been isolated from poly-m-phenylenesulfide and characterized.

  2. 2.

    Conformational rigidity of molecules of cyclotris(m-phenylenesulfide), in the presence of an insubstantial degree of strain for the macrocycle, has been established by x-ray structural analysis. The relatively low yields of larger macrocycles in the polycondensation reaction can be attributed to a greater degree of strain in these molecules, i.e., to larger energies of formation.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Sergeev, Yu. É. Ovchinnikov, V. I. Nedel'kin, A. V. Astankov, O. B. Andrianova, V. E. Shklover, I. A. Zamaev & Yu. T. Struchkov

Authors
  1. V. A. Sergeev
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  2. Yu. É. Ovchinnikov
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  3. V. I. Nedel'kin
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  4. A. V. Astankov
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  5. O. B. Andrianova
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  6. V. E. Shklover
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  7. I. A. Zamaev
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  8. Yu. T. Struchkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1625–1629, July, 1988.

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Sergeev, V.A., Ovchinnikov, Y.É., Nedel'kin, V.I. et al. Synthesis and crystal structure of cyclotris(m-phenylenesulfide). Russ Chem Bull 37, 1440–1444 (1988). https://doi.org/10.1007/BF00962758

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  • DOI: https://doi.org/10.1007/BF00962758

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