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Ethyl 4-thi0cyanato-3-oxo-2-arylhydrazono-1-butanoates in heterocyclization reactions

2. Synthesis and structure of 2-imino-5-[1-(arylhydrazono)-2-ethoxyoxalyl]-4,5-dehydro-1,3-oxathiolanes and 2-chloro-4-[1-(arylhydrazono)-2-ethoxyoxalyl]-1,3-thiazoles

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Substituted 1,3-oxathiolanes or substituted 2-chloro-1,3-thiazoles are formed in the reaction of ethyl 4-thiocyanato-3-oxo-2-arylhydrazono-1-butanoates with gaseous HCl in absolute benzene, depending on the electron-donor properties of the substituents in the arylhydrazone.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    M. O. Lozinskii, V. N. Bodnar, Yu. A. Sokolova, O. A. D'yachenko & L. O. Atovmyan

  2. Chernogolovka Branch, Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    M. O. Lozinskii, V. N. Bodnar, Yu. A. Sokolova, O. A. D'yachenko & L. O. Atovmyan

Authors
  1. M. O. Lozinskii
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  2. V. N. Bodnar
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  3. Yu. A. Sokolova
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  4. O. A. D'yachenko
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  5. L. O. Atovmyan
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1612–1618, July, 1988.

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Lozinskii, M.O., Bodnar, V.N., Sokolova, Y.A. et al. Ethyl 4-thi0cyanato-3-oxo-2-arylhydrazono-1-butanoates in heterocyclization reactions. Russ Chem Bull 37, 1428–1433 (1988). https://doi.org/10.1007/BF00962756

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  • DOI: https://doi.org/10.1007/BF00962756

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