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Preparation of pheromone components by cometathesis reactions in the presence of MoCl5/SiO2-R4Sn CATALYST

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The cometathesis of long-chain olefins and their functionalized derivatives has been carried out on a heterogeneous Mo catalyst, to give mixtures of geometric isomers of 9-tricosene and 9-tetradecenal, with cis/trans ratios of 16-18/84-82.

  2. 2.

    The rates of these cometathesis rections decrease in the transition from simple olefins to their functionalized derivatives.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    V. I. Bykov, T. A. Butenko, E. Sh. Finkel'shtein, P. V. Petrovskii & V. M. Vdovin

Authors
  1. V. I. Bykov
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  2. T. A. Butenko
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  3. E. Sh. Finkel'shtein
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  4. P. V. Petrovskii
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  5. V. M. Vdovin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 1580–1583, July, 1988.

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Bykov, V.I., Butenko, T.A., Finkel'shtein, E.S. et al. Preparation of pheromone components by cometathesis reactions in the presence of MoCl5/SiO2-R4Sn CATALYST. Russ Chem Bull 37, 1397–1400 (1988). https://doi.org/10.1007/BF00962749

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  • DOI: https://doi.org/10.1007/BF00962749

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