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Resonance raman light scattering spectra and cross section and the electronic structure of polyene compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have investigated the resonance Raman spectra of polyene ω-dimethylaminocarbonyl compounds and we have measured the absolute differential cross sections (ADC's) of the resonance Raman scattering at the maximum of the long-wavelength absorption band.

  2. 2.

    A polyene with two identical groups in the α and ω positions (or with two groups with identical electronegativity) has the same resonance Raman ADC as the unsubstituted compound with the same effective number of conjugated double bonds, but introduction of groups with sharply different electronegativity into the α and ω positions leads to significant decrease in the resonance Raman ADC.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. V. Berdyugin, K. Ya. Burshtein, N. A. Anikin, Zh. A. Krasnaya & T. S. Stytsenko

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  1. V. V. Berdyugin
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  2. K. Ya. Burshtein
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  3. N. A. Anikin
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  4. Zh. A. Krasnaya
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  5. T. S. Stytsenko
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1560–1565, July, 1988.

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Berdyugin, V.V., Burshtein, K.Y., Anikin, N.A. et al. Resonance raman light scattering spectra and cross section and the electronic structure of polyene compounds. Russ Chem Bull 37, 1378–1382 (1988). https://doi.org/10.1007/BF00962744

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  • DOI: https://doi.org/10.1007/BF00962744

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