Synthesis and study of transition metal complexes with iminodisuccinic acid

  • I. B. Kovaleva
  • N. D. Mitrofanova
  • L. I. Martynenko
  • V. I. Spitsyn
  • M. G. Felin
Inorganic Chemistry
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Conclusions

  1. 1.

    Protonated, neutral (mixed), and binuclear Cu(II), Ni(II), Co(II), Zn(II), and Mn(II) iminodisuccinate complexes have been synthesized.

     
  2. 2.

    Based on the results of IR-spectroscopic, thermal, and other methods of analysis, various conclusions have been drawn concerning the structures of these complexes; for instance, in the case of complexes of composition H2ML·nH2O both carboxyl groups are protonated, and one of them is coordinated to the metal ion.

     

Keywords

Carboxyl Metal Complex Transition Metal Complex Iminodisuccinic Acid 

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Literature cited

  1. 1.
    A. N. Perov, and V. I. Il'in, Problems in the Chemistry of Complexing Agents. Collection of Research Work, Kalinin State University Press, Kalinin (1985), p. 81.Google Scholar
  2. 2.
    V. I. Spitsyn et al. (eds.), Coordination Chemistry of Rare Earth Elements [in Russian], Moscow' State University Press, Moscow (1979), p. 85.Google Scholar
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    L. Bellamy, Infrared Spectra of Complex Molecules, 2nd ed., Methuen, London (1966).Google Scholar
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    I. P. Gorelov, V. M. Nikol'skii, and A. I. Kapustnikov, Zh. Obshch. Khim.,48, 2596 (1978).Google Scholar
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    L. M. Shkol'nikova, A. V. Gasparyan, M. A. Porai-Koshits, et al., Dokl. Akad. Nauk SSSR,283, No. 3, 649 (1985).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • I. B. Kovaleva
    • 1
  • N. D. Mitrofanova
    • 1
  • L. I. Martynenko
    • 1
  • V. I. Spitsyn
    • 1
  • M. G. Felin
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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