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Cycloaddition reactions of methyl 2-N-trifluoroacetyliminotrifluoropropionate

  • S. N. Osipov
  • A. F. Kolomiets
  • A. V. Fokin
Organic Chemistry

Conclusions

The methyl ester of 2-(N-trifluoroacetylimino)trifluoropropionic acid reacts with diazo-alkanes at the isolated C=N bond similarly to azomethines, forming [1+2]- and/or [3+2]-cycloadducts, and with unsaturated donating type compounds as a 1,3-dipolar conjugated system to give products of [2+4]-cycloaddition regio- and stereo-selectively.

Keywords

Methyl Ester Methyl Ester Cycloaddition Reaction Type Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    A. V. Fokin, A. F. Kolomiets, and N. V. Vasil'ev, Usp. Khim.,53, 398 (1984).Google Scholar
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    Yu. V. Zeifman, N. P. Gambaryan, L. A. Simonyan, et al., Zh. Obshch. Khim.,37, 2476 (1967).Google Scholar
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    L. N. Kryukov, L. Yu. Kryukova, and A. F. Kolomiets, Zh. Org. Khim.,18, 1873 (1982).Google Scholar
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    A. S. Onishchenko, Diene Synthesis [in Russian], Nauka, Moscow (1963), p. 38.Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • S. N. Osipov
    • 1
  • A. F. Kolomiets
    • 1
  • A. V. Fokin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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