Conclusions
The telomerization of vinyltrimethylsilane by ethanol is accompanied to a larger extent by rearrangement of MeCH(OH)CH2·CHSiMe3 radicals with 1,3-hydrogen atom migration and leads to the formation of secondary and tertiary silicon-containing alcohols as well as the products of their dehydration.
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Literature cited
R. Kh. Freidlina and A. B. Terent'ev, in: G. H. Williams (ed.), Advances in Free-Radical Chemistry, Vol. 6, Heyden (1980), p. 1.
A. B. Terent'ev and N. S. Ikonnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 1425 (1984).
A. B. Terent'ev, M. A. Moskalenko, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1800 (1985).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2179–2182, September, 1988.
The author expresses his gratitude to V. I. Dostovalova and L. I. Sheveleva for participating in carrying out this study.
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Terent'ev, A.B. Telomerization of vinyltrimethylsilane with alcohols. Russ Chem Bull 37, 1958–1961 (1988). https://doi.org/10.1007/BF00962527
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DOI: https://doi.org/10.1007/BF00962527