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Hydrolysis of fluoroalkyl-containing β,β'-triketones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The regioselective hydrolysis of 3-perfluoroacylpentane-2,4-diones in aqueous neutral and acid media may serve as a preparative method for obtaining fluoroalkyl-containing β-diketones.

  2. 2.

    The hydrolysis of 3-perfluoroacylpentane-2,4-diones in the presence of bases proceeds with the loss of the perfluoroacyl and acetyl groups to form acetylacetone and fluoroalkyl-containing β-diketones.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk

    V. M. Krokhalev, V. I. Saloutin & K. I. Pashkevich

Authors
  1. V. M. Krokhalev
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  2. V. I. Saloutin
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  3. K. I. Pashkevich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2177–2179, September, 1988.

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Krokhalev, V.M., Saloutin, V.I. & Pashkevich, K.I. Hydrolysis of fluoroalkyl-containing β,β'-triketones. Russ Chem Bull 37, 1956–1957 (1988). https://doi.org/10.1007/BF00962526

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  • DOI: https://doi.org/10.1007/BF00962526

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