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Transition metal σ-complexes in organic synthesis. 4. Cross coupling of allyl esters and allyl aryl sulfones with organotitanium compounds in the presence of palladium complexes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reactions of organotitanium compounds PhTi(OPr-i)3 and MeTi(OPr-i)3 with allyl acetates, allyl phenyl ethers, allyl aryl sulfones, and allylic tosylates and mesylates are catalyzed by Pd complexes and lead to the formation of cross-coupling products.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Scientific Center, Ural Branch, Academy of Sciences of the USSR, Ufa

    A. N. Kasatkin, A. N. Kulak, G. A. Tolstikov & S. I. Lomakina

Authors
  1. A. N. Kasatkin
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  2. A. N. Kulak
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  3. G. A. Tolstikov
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  4. S. I. Lomakina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2159–2166, September, 1988.

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Kasatkin, A.N., Kulak, A.N., Tolstikov, G.A. et al. Transition metal σ-complexes in organic synthesis. 4. Cross coupling of allyl esters and allyl aryl sulfones with organotitanium compounds in the presence of palladium complexes. Russ Chem Bull 37, 1939–1945 (1988). https://doi.org/10.1007/BF00962520

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  • DOI: https://doi.org/10.1007/BF00962520

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