Advertisement

Reaction of 1,1-dichloro-1-nitrosoalkanes with trivalent phosphorus acid chlorides

  • I. V. Martynov
  • A. N. Ivanov
  • T. A. Epishina
  • V. B. Sokolov
Organic Chemistry
  • 22 Downloads

Conclusions

1,1-Dichloro-1-nitrosoalkanes react with trivalent phosphorus acid chlorides not containing a P-O ether bond in the presence of nucleophilic reagents (sulfur dioxide, ethanethiol) to produce phosphorylated alkylchloroformoximes. This is rationalized in terms of intermediate O-alkylchloroformiminoyldichlorophosphorane formation.

Keywords

Sulfur Ether Chloride Phosphorus Dioxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    J. F. Allen, J. Am. Chera. Soc.,79, 3071 (1957).Google Scholar
  2. 2.
    I. V. Martynov, A. N. Ivanov, T. A. Epishina, and V. B. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., 2158 (1986).Google Scholar
  3. 3.
    G. M. Kosolapoff and L. Maier, Organic Phosphorus Compounds,3, 219 (1972).Google Scholar
  4. 4.
    S. I. Malekin, V. I. Yakutin, M. A. Sokal'skii, et al., Zh. Obshch. Khim.,42, 807 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • I. V. Martynov
    • 1
  • A. N. Ivanov
    • 1
  • T. A. Epishina
    • 1
  • V. B. Sokolov
    • 1
  1. 1.Institute for Physiologically Active SubstancesAcademy of of Sciences of the USSRChernogolovka

Personalised recommendations