Reaction of 1,1-dichloro-1-nitrosoalkanes with trivalent phosphorus acid chlorides

  • I. V. Martynov
  • A. N. Ivanov
  • T. A. Epishina
  • V. B. Sokolov
Organic Chemistry
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Conclusions

1,1-Dichloro-1-nitrosoalkanes react with trivalent phosphorus acid chlorides not containing a P-O ether bond in the presence of nucleophilic reagents (sulfur dioxide, ethanethiol) to produce phosphorylated alkylchloroformoximes. This is rationalized in terms of intermediate O-alkylchloroformiminoyldichlorophosphorane formation.

Keywords

Sulfur Ether Chloride Phosphorus Dioxide 

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Literature cited

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    G. M. Kosolapoff and L. Maier, Organic Phosphorus Compounds,3, 219 (1972).Google Scholar
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    S. I. Malekin, V. I. Yakutin, M. A. Sokal'skii, et al., Zh. Obshch. Khim.,42, 807 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • I. V. Martynov
    • 1
  • A. N. Ivanov
    • 1
  • T. A. Epishina
    • 1
  • V. B. Sokolov
    • 1
  1. 1.Institute for Physiologically Active SubstancesAcademy of of Sciences of the USSRChernogolovka

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