Conclusions
The formation of binuclear complexes by cyclopendant organophosphorus complexones was investigated. It was shown that the bond formed between the second cation and the M'L complex during the formation of the binuclear complex M'LM" (M' ≠ M") is predominantly ionic.
Similar content being viewed by others
Literature cited
M. I. Kabachnik, T. Ya. Medved', and Yu. M. Polikarpov, Izv. Akad. Nauk SSSR, Ser. Khim., 835 (1984).
M. I. Ka'bachnik, T. Ya. Medved', F. I. Bel'skii, and S. A. Pisareva, Izv. Akad. Nauk SSSR, Ser. Khim., 844 (1984).
S. A. Pisareva, F. I. Bel'skii, T. Ya. Medved', and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 413 (1987).
E. J. Durham and D. P. Ryskiewich, J. Am. Chem. Soc.,80, 4812 (1958).
G. Anderegg, P. Nageli, F. Müller, and G. Schwarzenbach, Helv. Chim. Acta,42, 827 (1959).
T. A. Bonigian and A. E. Martell, Inorg. Chem.,4, 1264 (1965).
W. Linden and G. Anderegg, Helv. Chim. Acta,53, 569 (1970).
Y. Moriguchi, M. Miyazaki, and K. Ueno, Bull. Chem. Soc. Jpn.,41, 1344 (1968).
M. I. Kabachnik, T. Ya. Medved', N. M. Dyatlova, and M. V. Rudomino, Usp. Khim.,43, 1554 (1974).
M. I. Kabachnik, N. M. Dyatlova, T. Ya. Medved', et al., Dokl. Akad. Nauk SSSR,164, 1311 (1965).
A. I. Grigor'ev, L. V. Nikitina, and N. M. Dyatlova, Zh. Neorg. Khim.,19, 1970 (1974).
L. V. Nikitina, A. I. Grigor'ev, and N. M. Dyatlova, Dokl. Akad. Nauk SSSR,217, 1359 (1974).
N. I. Voronezheva, A. I. Grigor'ev, and N. M. Dyatlova, Zh. Neorg. Khim.,21, 2051 (1976).
R. J. Grabensetter and W. A. Cilley, J. Phys. Chem.,75, 676 (1971).
G. Gross, T. Ya. Medved', S. Novak, et al., Zh. Obshch. Khim.,67, 734 (1985).
N. M. Dyatlova, V. V. Medyntsev, T. Ya. Medved', and M. I. Kabachnik, Zh. Obshch. Khim.,38C, 1065 (1968).
N. I. Voronezheva, Yu. V. Rudyak, N. M. Dyatlova, and A. I. Grigor'ev, Koord. Khim., No. 6, 991 (1980).
Author information
Authors and Affiliations
Additional information
Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2103–2107, September, 1988.
Rights and permissions
About this article
Cite this article
Medved', T.Y., Kabachnik, M.I., Bel'skii, F.I. et al. Formation of binuclear complexes by cyclopendant organophosphorus complexones. Russ Chem Bull 37, 1886–1890 (1988). https://doi.org/10.1007/BF00962507
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00962507