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Reactions of lithium, cobalt(ii), and copper(ii) ions with some phosphoryl- and acyl-methylenetriphenylphosphoranes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complexes of cobalt(II) chloride with diphenylphosphoryl-substituted acetyl- and benzoylmethylenetriphenylphosphoranes have been synthesized, and characterized by their stability constants in solution and absorption spectra in the visible and IR regions.

  2. 2.

    The stability constants of complexes of lithium [LiL]+ and copper(II) [CuLCl]+ have been measured in nonaqueous media for a number of methylenetriphenylphosphorane derivatives.

  3. 3.

    The introduction of an ylid p=C bond into compounds with acyl and (or) phosphoryl groups results in a marked increase in the complex-forming ability of these compounds.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    K. B. Yatsimirskii, É. I. Sinyavskaya, L. V. Tsymbal, T. A. Mastryukova, I. M. Aladzheva, I. V. Leont'eva & M. I. Kabachnik

  2. A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow

    K. B. Yatsimirskii, É. I. Sinyavskaya, L. V. Tsymbal, T. A. Mastryukova, I. M. Aladzheva, I. V. Leont'eva & M. I. Kabachnik

Authors
  1. K. B. Yatsimirskii
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  2. É. I. Sinyavskaya
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  3. L. V. Tsymbal
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  4. T. A. Mastryukova
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  5. I. M. Aladzheva
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  6. I. V. Leont'eva
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  7. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2094–2102, September, 1988.

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Yatsimirskii, K.B., Sinyavskaya, É.I., Tsymbal, L.V. et al. Reactions of lithium, cobalt(ii), and copper(ii) ions with some phosphoryl- and acyl-methylenetriphenylphosphoranes. Russ Chem Bull 37, 1879–1886 (1988). https://doi.org/10.1007/BF00962506

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  • DOI: https://doi.org/10.1007/BF00962506

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