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Reaction of allene cyclodimers with alkyllithium compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

1,3-Dimethylenecyclobutane and 1-methyl-3-methylenecyclobutene are metallated in the presence of THF by alkyllithium compounds under mild conditions with the formation of one and the same organolithium compound of the π-pentadienyl type. Under the same conditions, 1,2-dimethylenecyclobutane adds alkyllithium compounds, to form a π-alkenyl complex.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of USSR, Moscow

    A. V. Yurkovetskii, G. N. Bondarenko, V. D. Oppengeim & K. L. Makovetskii

Authors
  1. A. V. Yurkovetskii
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  2. G. N. Bondarenko
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  3. V. D. Oppengeim
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  4. K. L. Makovetskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1996–1999, September, 1988.

The authors wish to express their gratitude to E. R. Dolinskaya and her fellow workers for recording the spectra on the Bruker HX-270 spectrometer.

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Yurkovetskii, A.V., Bondarenko, G.N., Oppengeim, V.D. et al. Reaction of allene cyclodimers with alkyllithium compounds. Russ Chem Bull 37, 1785–1788 (1988). https://doi.org/10.1007/BF00962488

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  • DOI: https://doi.org/10.1007/BF00962488

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