Autocatalysis and effects of the solvent in the reaction of phthalic anhydride with aniline derivatives

  • K. K. Kalnin'sh
Physical Chemistry
  • 51 Downloads

Conclusions

  1. 1.

    A new method of analysis of autocatalytic reactions was developed which permits determining the rate constants of noncatalytic and catalytic reaction pathways with the data from one kinetic curve.

     
  2. 2.

    The reverse reaction of acylation has an autocatalytic character.

     
  3. 3.

    In comparison to CHCl3, in CH3CN, all of the rate constants increase by 2–4 times, and the noncatalytic reaction pathways are more sensitive to the nature of the solvent.

     

Keywords

CHCl3 Anhydride Aniline Catalytic Reaction CH3CN 

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Literature cited

  1. 1.
    M. I. Bessonov, M. M. Koton, V. V. Kudryavtsev, and L. A. Laius, Polyimides: A Class of Thermostable Polymers [in Russian], Nauka, Leningrad (1983).Google Scholar
  2. 2.
    L. M. Litvinenko, D. M. Aleksandrova, and S. F. Prokopovich, Ukr. Khim. Zh.,27, 494 (1961).Google Scholar
  3. 3.
    L. M. Litvinenko and D. M. Aleksandrova, Ukr. Khim. Zh.,27, 212 (1961).Google Scholar
  4. 4.
    A. N. Pravednikov, I. E. Kardash, I. P. Glukhoedov, and A. Ya. Ardashnikov, Vysokomol. Soedin.,15, 349 (1973).Google Scholar
  5. 5.
    A. I. Sadovnikov and L. V. Kuritsyn, Izv. Vuzov. Khim. Khim. Tekhnol.,24, 316 (1981).Google Scholar
  6. 6.
    A. I. Sadovnikov and L. V. Kuritsyn, Izv. Vuzov. Khim. Khim. Tekhnol.,24, 847 (1981).Google Scholar
  7. 7.
    K. K. Kalnin'sh and G. V. Lyubimova, Vysokomol. Soedin.,24, 1446 (1982).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • K. K. Kalnin'sh
    • 1
  1. 1.Institute of Macromolecular CompoundsAcademy of Sciences of the USSRLeningrad

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