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Encapsulation of gases by zeolites. 2. Encapsulation of nitrogen and oxygen by small-cavity type a zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been established experimentally that at 740 K and ∼90 MPa, approximately three molecules of N2 or O2 are adsorbed in a small cavity of NaA zeolite.

  2. 2.

    Analysis of the desorption curves indicates that for CsNaA zeolite (degree of exchange of Na+ by Cs+ 70%) it is impossible to distinguish quantitatively between adsorption in the large and the small cavities.

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Literature cited

  1. D. W. Breck, Zeolite Molecular Sieves: Structure, Chemistry, and Use, Wiley, New York (1974).

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    I. A. Kalinnikova, A. A. Pribylov, V. V. Serpinskii, T. N. Ivanova & S. M. Kalashnikov

Authors
  1. I. A. Kalinnikova
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  2. A. A. Pribylov
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  3. V. V. Serpinskii
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  4. T. N. Ivanova
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  5. S. M. Kalashnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1966–1968, September, 1988.

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Kalinnikova, I.A., Pribylov, A.A., Serpinskii, V.V. et al. Encapsulation of gases by zeolites. 2. Encapsulation of nitrogen and oxygen by small-cavity type a zeolites. Russ Chem Bull 37, 1756–1758 (1988). https://doi.org/10.1007/BF00962480

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  • DOI: https://doi.org/10.1007/BF00962480

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