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Initiated oxidation of dibutyl ether in the presence of inhibitors

  • N. V. Zolotova
  • V. V. Kharitonov
Inorganic Chemistry

Abstract

It was found that unlike ionol, amines effectively inhibit the oxidation of dibutyl ether. The stoichiometric inhibition coefficient for amines is close to two. During the initiated oxidation of dibutyl ether in the presence of inhibitors, an exchange takes place of cyanoisopropyl peroxy radicals for the peroxy radicals of dibutyl ether. The mechanism of the reaction with p-phenylenediamine (p-PDA) probably consists in the formation of a fairly stable complex consisting of an amine molecule and two peroxy radicals. This reaction does not result in the formation of a hydroperoxide.

Keywords

Oxidation Ether Hydroperoxide Stable Complex Peroxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • N. V. Zolotova
    • 1
  • V. V. Kharitonov
    • 1
  1. 1.N. N. Semenov Institute of Chemical PhysicsAcademy of Sciences of the USSR, Chernogolovka BranchUSSR

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