Conclusions
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1.
A method is proposed for the preparation of 1-germatranols with the general formula
(R=Me, Ph, n=0-3, m=0.1) by the reaction of germanium dioxide with tris(2-hydroxyalkyl)amines by heating in an aqueous medium.
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2.
For the first time, C-substituted 1-germatranols (R=Me, n=1, m=1; R=Me, n=2–3, m=0; R=Ph, n=1, m=0) were obtained and characterized.
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E. E. Shestakov, M. G. Voronkov, Yu. L. Frolov, and V. P. Baryshok, Zh. Obshch. Khim.,53, 1298 (1983).
V. E. Shklover, Yu. T. Struchkov, M. G. Voronkov, et al., Dokl. Akad. Nauk SSSR,277, 1185 (1984).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 880–882, April, 1987.
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Voronkov, M.G., Ovchinnikova, Z.A. & Baryshok, V.P. Synthesis of 1-germatranol and its C-substituted derivatives. Russ Chem Bull 36, 806–808 (1987). https://doi.org/10.1007/BF00962326
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DOI: https://doi.org/10.1007/BF00962326