Conclusions
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1.
Oxidative dimerization of the Ni(II) complexes of the Schiff's base of S,R-alanine with S-2-N-(N′-benzylprolyl)aminobenzaldehyde has been carried out, to give following de-composition of the dimeric complex (2S,3S)-2,3-diamino-2,3-dimethylsuccinic acid.
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2.
C-Alkenylation of glycine in the Ni(II) complex of its Schiff's base with S-2-N-(N′-benzylprolyl)aminobenzophenone by treatment with CH2Br2 followed by decomposition of the alkenylated complex has given (2S,4S)-diaminoglutaric acid.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 852–857, April, 1987.
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Belokon', Y.N., Chernoglazova, N.I., Batsanov, A.S. et al. Asymmetric synthesis of (2S,4S)-2,4-diaminoglutaric and (2S,3S)-2,3-diamino-2, 3-dimethylsuccinic acids using chiral Ni(II) complexes. Russ Chem Bull 36, 779–784 (1987). https://doi.org/10.1007/BF00962319
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DOI: https://doi.org/10.1007/BF00962319