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Calculation and experimental determination of rotational and forward motion of molecules in different solvents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On the basis of an analysis of 53 correlation times and diffusion coefficients of molecules it has been shown that a modified Kirkwood-Steele-Huntress equation predicts the correlation times and the diffusion coefficients in unassociated solvents with a precision of ∼15%.

  2. 2.

    It has been confirmed experimentally with within the framework of this theory it is possible to compute the coefficients of forward diffusion from the values of the correlation theories, and vice versa.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    V. A. Daragan & E. É. Il'ina

Authors
  1. V. A. Daragan
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  2. E. É. Il'ina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 782–786, April, 1987.

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Daragan, V.A., Il'ina, E.É. Calculation and experimental determination of rotational and forward motion of molecules in different solvents. Russ Chem Bull 36, 710–713 (1987). https://doi.org/10.1007/BF00962305

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  • DOI: https://doi.org/10.1007/BF00962305

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