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Application of13C NMR in studying the dynamics and structure of liquid phenol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Correlation times τ of rotational motion of liquid phenol have been measured over a broad temperature range, as well as the correlation times of certain organic compounds dissolved in phenol.

  2. 2.

    The non-Arrhenius temperature dependences of τ, together with the temperaturerelated changes in anisotropy of rotation of the “guest” molecules, indicate strong association of phenol molecules.

  3. 3.

    By means of a modification of the theory of Steele and Huntress, the temperature dependence of τ has been calculated for phenol monomers, and it has been shown that void spaces may be formed in the phenol structure, with most probable dimensions 5–10 Å.

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Literature cited

  1. H. J. Bender and H. G. Hertz, Ber. Bunsenges, Phys. Chem.,81, 468 (1977).

    Google Scholar 

  2. V. A. Daragan, A. U. Stepanyants, and T. N. Khazanovich, Zh. Struct. Khim.,19, 474 (1978).

    Google Scholar 

  3. O. D. Vetrov, V. A. Daragan, and I. V. Edneral, Khim. Fiz.,1, 1490 (1982).

    Google Scholar 

  4. V. A. Daragan and E. É. Il'ina, Khim. Fiz.,4, 405 (1985).

    Google Scholar 

  5. A. M. Gladkii, V. A. Daragan, and I. V. Edneral, Khim., Fiz.,4, 506 (1985).

    Google Scholar 

  6. V. A. Daragan and E. É. Il'ina, Izv. Akad. Nauk SSSR, Ser. Khim., p. 782 (1987).

  7. T. S. Farrar and E. D. Becker, Introduction to Pulse and Fourier-Transform NMR Methods, Academic Press, New York (1971).

    Google Scholar 

  8. V. Trepădus, S. Răpeanu, and R. Grosscu, Rev. Roum. Phys.,18, 313 (1973).

    Google Scholar 

  9. G. C. Levy, J. D. Cargioli, and F. A. L. Anet, J. Am. Chem. Soc.,95, 157 (1973).

    Google Scholar 

  10. A. I. Kitaigorodskii, Mixed Crystals [in Russian], Nauka, Moscow (1983).

    Google Scholar 

  11. W. T. Huntress, Adv. Magn. Reson.,4, 2 (1970).

    Google Scholar 

  12. M. Saunders and J. B. Hyne, J. Chem. Phys.,29, 1319 (1958).

    Google Scholar 

  13. E. D. Becker, J. Chem. Phys.,31, 269 (1959).

    Google Scholar 

  14. A. L. Porte, H. S. Gutowsky, and J. M. Hunsberger, J. Am. Chem. Soc.,82, 5057 (1960).

    Google Scholar 

  15. R. Mecke, Discuss. Faraday Soc.,9, 161 (1950).

    Google Scholar 

  16. M. Ito, J. Mol. Spectrosc.,4, 125 (1960).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. M. Aparkin & V. A. Daragan

Authors
  1. A. M. Aparkin
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  2. V. A. Daragan
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 778–782, April, 1987.

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Aparkin, A.M., Daragan, V.A. Application of13C NMR in studying the dynamics and structure of liquid phenol. Russ Chem Bull 36, 706–709 (1987). https://doi.org/10.1007/BF00962304

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  • DOI: https://doi.org/10.1007/BF00962304

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