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15N and17O NMR spectra of vinyl ethers of pyridine and quinoline

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

15N (14N) and17O NMR spectra have been obtained on vinyl ethers of pyridine and quinoline, with unenriched samples. The principal factor determining the chemical shifts is p-π conjugation of the unshared pairs of the heteroatom with the unsaturated fragments of the molecule; an additional contribution in the case of the15N signals comes from interaction of the nitrogen atom with a proton through space.

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Authors and Affiliations

  1. Siberian Branch, Irkutsk Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    A. V. Afonin, V. K. Voronov, E. I. Enikeeva & M. A. Andrayankov

Authors
  1. A. V. Afonin
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  2. V. K. Voronov
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  3. E. I. Enikeeva
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  4. M. A. Andrayankov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 769–773, April, 1987.

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Afonin, A.V., Voronov, V.K., Enikeeva, E.I. et al. 15N and17O NMR spectra of vinyl ethers of pyridine and quinoline. Russ Chem Bull 36, 697–700 (1987). https://doi.org/10.1007/BF00962302

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  • DOI: https://doi.org/10.1007/BF00962302

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