Skip to main content
Log in

Establishing the configuration of imine nitrogen compounds: Influence of alkyl groups on13C-13C spin-spin coupling constant in alkyl phenyl ketoximes

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In a series of alkyl phenyl ketoximes, the constant of spin-spin coupling of the oxime carbon with the α-carbon atom of the phenyl group is determined by the inductive effect of the alkyl groups; this makes it possible to identify configurational isomers of similar compounds of imine nitrogen in those cases in which the corresponding carbon-carbon can be measured only in one isomer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. L. B. Krivdin, G. A. Kalabin, R. N. Nesterenko, and B. A. Trofimov, Tetrahedron Lett.,25, 4817 (1984).

    Google Scholar 

  2. L. B. Krivdin, G. A. Kalabin, R. N. Nesterenko, and B. A. Trofimov, Zh. Org. Khim.,20, 2477 (1984).

    Google Scholar 

  3. L. B. Krivdin, G. A. Kalabin, S. E. Korostova, S. G. Shevchenko, and B. A. Trofimov, Izv. Akad. Nauk SSSR, Ser. Khim., p. 2832 (1984).

  4. L. B. Krivdin, G. A. Kalabin, R. N. Nesterenko, and B. A. Trofimov, Khim. Geterotsikl. Soedin., p. 709 (1985).

  5. B. A. Trofimov and A. I. Mikhaleva, N-Vinylpyrroles [in Russian], Nauka, Novosibirsk (1984).

    Google Scholar 

  6. H. Gilman, A. H. Blatt, ed., Organic Syntheses, Vol. 2, Wiley-Interscience, New York (1941).

    Google Scholar 

  7. J. H. Smith, J. Org. Chem.,8, 728 (1974).

    Google Scholar 

  8. A. Bax, R. Freeman, and S. P. Kempsell, J. Am. Chem. Soc.,102, 507 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 766–769, April, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krivdin, L.B., Shcherbakov, V.V., Korostova, S.E. et al. Establishing the configuration of imine nitrogen compounds: Influence of alkyl groups on13C-13C spin-spin coupling constant in alkyl phenyl ketoximes. Russ Chem Bull 36, 694–697 (1987). https://doi.org/10.1007/BF00962301

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962301

Keywords

Navigation