Skip to main content
SpringerLink
Log in

Thermodynamic parameters of dehydrogenation reactions of normal paraffins with a C10-C15 hydrocarbon composition to olefins

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The enthalpy and entropy differences for the formation of 1-alkenes, as well as n-olefins with a double bond in an internal position in the cis and trans forms, as a result of the dehydrogenation of C10-C15 n-paraffins under standard conditions have been calculated.

  2. 2.

    Relations for the calculation of the thermodynamic parameters of the reactions (the enthalpy and entropy differences) from group contributions have been derived. Satisfactory agreement between the results obtained on the basis of the calculated and reference data has been demonstrated.

  3. 3.

    The enthalpy and entropy differences for the formation of n-olefins are practically not dependent on the length of the hydrocarbon chain and are determined by the position of the double bond in the molecule of the n-olefin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. D. R. Stull, E. F. Westrum, Jr., and G. C. Sinke, Chemical Thermodynamics of Organic Compounds, Wiley, New York (1969).

    Google Scholar 

  2. S. W. Benson and J. H. Buss, J. Chem. Phys.,29, 546 (1958).

    Google Scholar 

  3. S. W. Benson et al., Chem. Rev.,69, 279 (1969).

    Google Scholar 

  4. N. A. Eliseev, O. D. Sterligov, and G. V. Isagulyants, Izv. Vys. Uchebn. Zaved., Khim. Khim. Tekhnol.,27, No. 6, 644 (1984).

    Google Scholar 

  5. V. A. Kireev, Methods of Practical Calculations in the Thermodynamics of Chemical Reactions [in Russian], Khimiya, Moscow (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. A. Eliseev, O. D. Sterligov & G. V. Isagulyants

  2. Kaluzh Branch, N. E. Bauman Higher Technical School, Moscow

    N. A. Eliseev, O. D. Sterligov & G. V. Isagulyants

Authors
  1. N. A. Eliseev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. D. Sterligov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Isagulyants
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 745–748, April, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eliseev, N.A., Sterligov, O.D. & Isagulyants, G.V. Thermodynamic parameters of dehydrogenation reactions of normal paraffins with a C10-C15 hydrocarbon composition to olefins. Russ Chem Bull 36, 674–677 (1987). https://doi.org/10.1007/BF00962295

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962295

Keywords

Search

Navigation