Conclusions
We synthesized the monomer, 3-0-acetyl-4-0-(2,3,4-tri-0-acetyl-6-0-trityl-Β-D-glucopyranosyl)-1,2-0-exo-cyanoethylidene-Β-L-rhamnopyranose, and accomplished its polycondensation, as a result of which a stereoregular glucorhamnan was obtained.
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See [1] for Communication 11.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 200–204, January, 1981.
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Kochetkov, N.K., Klimov, E.M. Synthesis of polysaccharides. 12. Synthesis of regular glucorhamnan\( \mapsto ( \to 6 - D - Glcp1\xrightarrow{\beta }4Rhap1\xrightarrow{\alpha })\xrightarrow[n]{}\) . Russ Chem Bull 30, 179–182 (1981). https://doi.org/10.1007/BF00962279
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DOI: https://doi.org/10.1007/BF00962279