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Synthesis and properties of esters and amido esters of 1-(2-thienyl)-2,2,2-trichloroethylphosphorous acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The esterification of amido- and ester-amidophosphites with 1-(2-thienyl)-2,2,2-trichloroethanol gave the l-(2-thienyl)-2,2,2-trichloroethyl dialkyl- and 1-(2-thienyl)-2,2,2-trichloroethyl alkylamidophosphites, which easily add sulfur or are oxidized to the corresponding thiophosphates and phosphates.

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Literature cited

  1. U. S. Patent 2,865,929 (1958); C. A.,53, 8163b (1959).

  2. German Patent 2,605,649 (1976); C. A.86, 5631g (1977).

  3. South African Patent 6,605,579 (1968); C.A.,70, 57617f (1969).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 182–187, January, 1981.

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Nikonorov, K.V., Gurylev, é.A. & Mertsalova, F.F. Synthesis and properties of esters and amido esters of 1-(2-thienyl)-2,2,2-trichloroethylphosphorous acid. Russ Chem Bull 30, 161–166 (1981). https://doi.org/10.1007/BF00962275

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  • DOI: https://doi.org/10.1007/BF00962275

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