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Synthesis and reactivity of acid chlorides of aliphatic Β-(chlorosulfinyl)carboxylic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A convenient general method was developed for obtaining the acid chlorides of Β-(chlorosulfinyl)carboxylic acids from Β-(acetylthio)carboxylic acids.

  2. 2.

    The acid chlorides of Β-(chlorosulfinyl) carboxylic acids react with water and amines as the acid chloride form, while with alcohols, PCl3, and PCl5 they apparently react via the tautomeric form of the cyclic dichlorosulfuran.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. P. Vasil'eva, M. G. Lin'kova, O. V. Kil'disheva & I. L. Knunyants

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  1. T. P. Vasil'eva
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  2. M. G. Lin'kova
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  3. O. V. Kil'disheva
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 159–165, January, 1981.

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Vasil'eva, T.P., Lin'kova, M.G., Kil'disheva, O.V. et al. Synthesis and reactivity of acid chlorides of aliphatic Β-(chlorosulfinyl)carboxylic acids. Russ Chem Bull 30, 137–143 (1981). https://doi.org/10.1007/BF00962270

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  • DOI: https://doi.org/10.1007/BF00962270

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