Conclusions
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1.
The polarizability ellipsoids of the epoxy ring and the C-C and C-H bonds adjacent to it have been determined.
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2.
The absolute configuration and spatial structure of theα- andΒ-oxides of δ3-carene has been confirmed.
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Literature cited
S. G. Vul'fson and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim.,1979, 1574.
D. D. Fitts, in: A. Weissberger (editor), Physical Methods of Organic Chemistry, Part 3, Interscience, New York-London (1960).
B. A. Arbuzov, L. K. Novikova-Aleksandrova, S. G. Vul'fson, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 1932.
N. M. Walborsky and C. G. Pitt, J. Am. Chem. Soc.,84, 4831 (1962).
H. J. Lucas and H. K. Garner, J. Am. Chem. Soc.,72, 2145 (1950).
J. D. Swalen and D. R. Herschbach, J. Chem. Phys.,27, 100 (1957).
S. G. Vul'fson, Dissertation, Kazan' (1969).
B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Teor. Eksp. Khim.,4, 367 (1968).
R. J. W. Le Fevre, Adv. Phys. Org. Chem.,3, 1 (1965).
G. L. Cunnigham, A. W. Boyd, R. L. Meyers, W. D. Gwinn, and W. J. Le Van, J. Chem. Phys.,19, 676 (1951).
W. W. Wood, W. Fickett, and J. G. Kirkwood, J. Chem. Phys.,20, 561 (1952); M. V. Vol'kenshtein, Dokl. Akad. Nauk SSSR,71, 447 (1950).
K. Gollnick and G. Schade, Liebigs Ann. Chem.,721, 133 (1969).
V. A. Naumov, Dissertation, Kazan' (1972).
B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and Z. G. Isaeva, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 1966.
B. A. Arbuzov, Yu. Yu. Samitov, A. V. Aganov, and Yu. L. Kleiman, Dokl. Akad. Nauk SSSR,184, 341 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 117–120, January, 1981.
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Vul'fson, S.G. Absolute configuration and anisotropic polarizability of molecules. 2. Determination of polarizability ellipsoids of bonds inα-oxides from optical-activity data. Russ Chem Bull 30, 95–98 (1981). https://doi.org/10.1007/BF00962261
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DOI: https://doi.org/10.1007/BF00962261