Comparative catalytic efficiency of 1,4-dialkyl-1,4-diazoniabicyclo[2.2.2]octane difluorides and alkali metal fluorides in the reaction of pentafluorophenol with pentafluoropyridine

  • V. V. Aksenov
  • V. I. Vysochin
  • P. P. Rodionov
  • G. V. Shishkin
  • G. G. Yakobson
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Conclusions

The catalytic efficiency of 1,4-dialkyl-1,4-diazoniabicyclo[2.2.2]octane difluorides in the reaction of pentafluorophenol with pentafluoropyridine is somewhat enhanced with increasing length of the alkyl substituents and is higher than for LiF and NaF but markedly less than for KF and CsF.

Keywords

Fluoride Alkali Metal Octane Catalytic Efficiency Alkyl Substituent 

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • V. V. Aksenov
    • 1
    • 2
    • 3
  • V. I. Vysochin
    • 1
    • 2
    • 3
  • P. P. Rodionov
    • 1
    • 2
    • 3
  • G. V. Shishkin
    • 1
    • 2
    • 3
  • G. G. Yakobson
    • 1
    • 2
    • 3
  1. 1.Novosibirsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR
  2. 2.Novosibirsk Institute of Bioorganic Chemistry, Siberian DivisionAcademy of Sciences of the USSRUSSR
  3. 3.Lenin Komsomol Novosibirsk State UniversityUSSR

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